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National Emissions Standards for Hazardous Air Pollutants
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    National Emissions Standards for Hazardous Air Pollutants

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    The National Emission Standards for Hazardous Air Pollutants (NESHAP) are air pollution standards issued by the United States Environmental Protection Agency (EPA). The standards, authorized by the Clean Air Act, are for pollutants not covered by the National Ambient Air Quality Standards (NAAQS) that may cause an increase in fatalities or in serious, irreversible, or incapacitating illness.

    Maximum Achievable Control Technology standards

    The standards for a particular source category require the maximum degree of emission reduction that the EPA determines to be achievable, which is known as the Maximum Achievable Control Technology (MACT) standards. These standards are authorized by Section 112 of the 1970 Clean Air Act and the regulations are published in the Code of Federal Regulations (CFR).

    Pollutants

    EPA regulates the following hazardous air pollutants with the MACT standards.

    CAS Number Chemical Name Notes
    75-07-0 Acetaldehyde
    60-35-5 Acetamide
    75-05-8 Acetonitrile
    98-86-2 Acetophenone (Methyl Phenyl Ketone)
    53-96-3 2-Acetylaminofluorene
    107-02-8 Acrolein
    79-06-1 Acrylamide
    79-10-7 Acrylic acid
    107-13-1 Acrylonitrile
    107-05-1 Allyl chloride (3-Chloropropene)
    92-67-1 4-Aminobiphenyl
    62-53-3 Aniline
    90-04-0 o-Anisidine
    1332-21-4 Asbestos
    71-43-2 Benzene including benzene from gasoline
    92-87-5 Benzidine
    98-07-7 Benzotrichloride
    100-44-7 Benzyl chloride
    92-52-4 Biphenyl
    117-81-7 Bis(2-ethylhexyl)phthalate (DEHP)
    542-88-1 Bis(chloromethyl)ether
    75-25-2 Bromoform (Tribromomethane)
    106-99-0 1,3-Butadiene
    156-62-7 Calcium cyanamide
    105-60-2 Caprolactam Delisted on June 18, 1996
    133-06-2 Captan
    63-25-2 Carbaryl
    75-15-0 Carbon disulfide
    56-23-5 Carbon tetrachloride (Tetrachloromethane)
    463-58-1 Carbonyl sulfide
    120-80-9 Catechol
    133-90-4 Chloramben
    57-74-9 Chlordane
    7782-50-5 Chlorine
    79-11-8 Chloroacetic acid
    532-27-4 2-Chloroacetophenone
    108-90-7 Chlorobenzene
    510-15-6 Chlorobenzilate
    67-66-3 Chloroform (Trichloromethane)
    107-30-2 Chloromethyl methyl ether
    126-99-8 Chloroprene
    1319-77-3 Cresols/Cresylic acid (isomers and mixture)
    95-48-7 o-Cresol
    108-39-4 m-Cresol
    106-44-5 p-Cresol
    98-82-8 Cumene
    94-75-7 2,4-D, salts and esters
    3547-04-4 Dichlorodiphenyldichloroethylene (DDE)
    334-88-3 Diazomethane
    132-64-9 Dibenzofurans
    96-12-8 1,2-Dibromo-3-chloropropane (DBCP)
    84-74-2 Dibutylphthalate
    106-46-7 1,4-Dichlorobenzene (p-Dichlorobenzene)
    91-94-1 3,3'-Dichlorobenzidine
    111-44-4 Dichloroethyl ether (Bis(2-chloroethyl)ether)
    542-75-6 1,3-Dichloropropene
    62-73-7 Dichlorvos
    111-42-2 Diethanolamine
    64-67-5 Diethyl sulfate
    119-90-4 3,3'-Dimethoxybenzidine
    60-11-7 Dimethyl aminoazobenzene
    119-93-7 3,3'-Dimethyl benzidine
    79-44-7 Dimethylcarbamoyl chloride
    68-12-2 Dimethyl formamide
    57-14-7 1,1-Dimethyl hydrazine
    131-11-3 Dimethyl phthalate
    77-78-1 Dimethyl sulfate
    121-69-7 N,N-Dimethylaniline Clean Air Act erroneously lists N,N-Diethylaniline
    534-52-1 4,6-Dinitro-o-cresol, and salts
    51-28-5 2,4-Dinitrophenol
    121-14-2 2,4-Dinitrotoluene
    123-91-1 1,4-Dioxane (1,4-Diethyleneoxide)
    122-66-7 1,2-Diphenylhydrazine
    106-89-8 Epichlorohydrin (l-Chloro-2,3-epoxypropane)
    106-88-7 1,2-Epoxybutane
    140-88-5 Ethyl acrylate
    100-41-4 Ethyl benzene
    51-79-6 Ethyl carbamate (Urethane)
    75-00-3 Ethyl chloride (Chloroethane)
    106-93-4 Ethylene dibromide (1,2-Dibromoethane)
    107-06-2 Ethylene dichloride (1,2-Dichloroethane)
    107-21-1 Ethylene glycol
    151-56-4 Ethylene imine (Aziridine)
    75-21-8 Ethylene oxide
    96-45-7 Ethylene thiourea
    75-34-3 Ethylidene dichloride (1,1-Dichloroethane)
    50-00-0 Formaldehyde
    76-44-8 Heptachlor
    118-74-1 Hexachlorobenzene
    87-68-3 Hexachlorobutadiene
    77-47-4 Hexachlorocyclopentadiene
    67-72-1 Hexachloroethane
    822-06-0 Hexamethylene-1,6-diisocyanate
    680-31-9 Hexamethylphosphoramide
    110-54-3 Hexane
    302-01-2 Hydrazine
    7647-01-0 Hydrochloric acid
    7664-39-3 Hydrogen fluoride (Hydrofluoric acid)
    7783-06-4 Hydrogen sulfide Delisted on December 4, 1991
    123-31-9 Hydroquinone
    78-59-1 Isophorone
    58-89-9 Lindane (all isomers)
    108-31-6 Maleic anhydride
    67-56-1 Methanol
    72-43-5 Methoxychlor
    74-83-9 Methyl bromide (Bromomethane)
    74-87-3 Methyl chloride (Chloromethane)
    71-55-6 Methyl chloroform (1,1,1-Trichloroethane)
    78-93-3 Methyl ethyl ketone (2-Butanone or MEK) Delisted on December 19, 2005
    60-34-4 Methyl hydrazine
    74-88-4 Methyl iodide (Iodomethane)
    108-10-1 Methyl isobutyl ketone (Hexone or MIBK) currently under review for delisting
    624-83-9 Methyl isocyanate
    80-62-6 Methyl methacrylate
    1634-04-4 Methyl tert-butyl ether
    101-14-4 4,4'-Methylene bis(2-chloroaniline)
    75-09-2 Methylene chloride (Dichloromethane)
    101-68-8 Methylene diphenyl diisocyanate (MDI) currently under review for delisting
    101-77-9 4,4'-Methylenedianiline
    91-20-3 Naphthalene
    98-95-3 Nitrobenzene
    92-93-3 4-Nitrobiphenyl
    100-02-7 4-Nitrophenol
    79-46-9 2-Nitropropane
    684-93-5 N-Nitroso-N-methylurea
    62-75-9 N-Nitrosodimethylamine
    59-89-2 N-Nitrosomorpholine
    56-38-2 Parathion
    82-68-8 Pentachloronitrobenzene (Quintobenzene)
    87-86-5 Pentachlorophenol
    108-95-2 Phenol
    106-50-3 p-Phenylenediamine
    75-44-5 Phosgene
    7803-51-2 Phosphine
    7723-14-0 Phosphorus
    85-44-9 Phthalic anhydride
    1336-36-3 Polychlorinated biphenyls (Aroclors)
    1120-71-4 1,3-Propane sultone
    57-57-8 beta-Propiolactone
    123-38-6 Propionaldehyde
    114-26-1 Propoxur (Baygon)
    78-87-5 Propylene dichloride (1,2-Dichloropropane)
    75-56-9 Propylene oxide
    75-55-8 1,2-Propylenimine (2-Methyl aziridine)
    91-22-5 Quinoline
    106-51-4 Quinone
    100-42-5 Styrene
    96-09-3 Styrene oxide
    1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin
    79-34-5 1,1,2,2-Tetrachloroethane
    127-18-4 Tetrachloroethylene (Perchloroethylene)
    7550-45-0 Titanium tetrachloride
    108-88-3 Toluene
    95-80-7 2,4-Toluene diamine
    584-84-9 2,4-Toluene diisocyanate
    95-53-4 o-Toluidine
    8001-35-2 Toxaphene (chlorinated camphene)
    120-82-1 1,2,4-Trichlorobenzene
    79-00-5 1,1,2-Trichloroethane
    79-01-6 Trichloroethylene
    95-95-4 2,4,5-Trichlorophenol
    88-06-2 2,4,6-Trichlorophenol
    121-44-8 Triethylamine
    1582-09-8 Trifluralin
    540-84-1 2,2,4-Trimethylpentane
    108-05-4 Vinyl acetate
    593-60-2 Vinyl bromide (Bromoethene)
    75-01-4 Vinyl chloride (Chloroethene)
    75-35-4 Vinylidene chloride (1,1-Dichloroethylene)
    1330-20-7 Xylenes (isomers and mixture)
    95-47-6 o-Xylenes
    108-38-3 m-Xylenes
    106-42-3 p-Xylenes
    n/a Antimony Compounds
    n/a Arsenic Compounds inorganic including arsine
    n/a Beryllium Compounds
    n/a Cadmium Compounds
    n/a Chromium Compounds
    n/a Cobalt Compounds
    n/a Coke Oven Emissions
    n/a Cyanide Compounds
    n/a Glycol ethers
    n/a Lead Compounds
    n/a Manganese Compounds
    n/a Mercury Compounds
    n/a Fine mineral fibers
    n/a Nickel Compounds
    n/a Polycylic Organic Matter
    n/a Radionuclides including radon
    n/a Selenium Compounds

    For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) as part of that chemical's infrastructure.

    n = 1, 2, or 3
    R = alkyl C7 (chain of 7 carbon atoms) or less; or phenyl or alkyl substituted phenyl
    R' = H or alkyl C7 or less; or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Polymers are excluded from the glycol category, as well as surfactant alcohol ethoxylates (where R is an alkyl C8 or greater) and their derivatives, and ethylene glycol monobutyl ether (CAS 111-76-2).
    • ^3 Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less.
    • ^4 Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 °C.
    • ^5 A type of atom which spontaneously undergoes radioactive decay.

    Pollution sources

    Most air toxics originate from human-made sources, including mobile sources (e.g., cars, trucks, buses) and stationary sources (e.g., factories, oil refineries, power plants), as well as indoor sources (e.g., building materials and activities such as cleaning). There are two types of stationary sources that generate routine emissions of air toxics:

    1. Major sources are defined as sources that emit 10 or more tons per year of any of the listed toxic air pollutants, or 25 or more tons per year of a mixture of air toxics. These sources may release air toxics from fugitive emissions (equipment leaks), when materials are transferred from one location to another, or during discharge through emission stacks or vents.
    2. Area sources consist of smaller facilities that release lesser quantities of toxic pollutants into the air. Area sources are defined as sources that do not emit more than 10 tons per year of a single air toxic or more than 25 tons per year of a combination of air toxics. Although the emissions from individual area sources are often relatively small, collectively their emissions can be of concern, particularly where large numbers of sources are located in heavily populated areas.

    EPA published its initial list of source categories in 1992. Subsequently the agency issued several revisions and updates to the list and the regulatory promulgation schedule. For each listed source category, EPA indicates whether the sources are considered to be major sources or area sources. The 1990 Clean Air Act Amendments direct EPA to set standards for all major sources of air toxics, and for some area sources that are of particular concern. EPA is required to review all source category regulations every eight years.

    See also

    External links


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