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Chemical safety

ADR (treaty)

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ADR (treaty)

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Members of the ADR treaty.

Non-members.

ADR, formally the Agreement of 30 September 1957 concerning the International Carriage of Dangerous Goods by Road is a 1957 United Nations treaty that governs transnational transport of hazardous materials. "ADR" is derived from the French name for the treaty: Accord relatif au transport international des marchandises Dangereuses par Route). Until 31 December 2020, the treaty was fully named European Agreement concerning the International Carriage of Dangerous Goods by Road. However, as the word "European" might have given the impression that the treaty was only open for accession to European states, an amendment was decided in the end of 2019.

Concluded in Geneva on 30 September 1957 under the aegis of the United Nations Economic Commission for Europe, it entered into force on 29 January 1968. The agreement was modified (article 14, paragraph 3) in New York City on 21 August 1975, though these changes only took effect on 19 April 1985. A new amended ADR 2011 entered into force on 1 January 2011. Annexes A and B have been regularly amended and updated since the entry into force of ADR. Consequently, to the amendments for entry into force on 1 January 2015 (until June 2017), a revised consolidated version has been published as document ECE/TRANS/242, Vol. I and II. Every two years the regulations are updated with the latest version applicable being the ADR 2021

As of 2022, 54 states are party to ADR.

The agreement itself is brief and simple, and its most important article is article 2. This article states that with the exception of certain exceptionally dangerous materials, hazardous materials may in general be transported internationally in wheeled vehicles, provided that two sets of conditions be met:

Annex A regulates the merchandise involved, notably their packaging and labels.
Annex B regulates the construction, equipment, and use of vehicles for the transport of hazardous materials.

The appendices consist of nine chapters, with the following contents

General provisions: terminology, general requirements
Classification: classification of dangerous goods (CDG)
Dangerous Goods List sorted by UN number, with references to specific requirements set in chapters 3 to 9; special provisions and exemptions related to dangerous goods packed in limited quantities
Packaging and tank provisions
Consignment procedures, labeling, and marking of containers and vehicles.
Construction and testing of packagings, intermediate bulk containers (IBCs), large packagings, and tanks
Conditions of carriage, loading, unloading, and handling
Vehicle crews, equipment, operation, and documentation
Construction and approval of vehicles

Hazard classes

The classes of dangerous goods according to ADR are the following:

Class 1 Explosive substances and articles
Class 2 Gases, including compressed, liquified, and dissolved under pressure gases and vapors
- Flammable gases (e.g. butane, propane, acetylene)
- Non-flammable and non-toxic, likely to cause asphyxiation (e.g. nitrogen, CO₂) or oxidisers (e.g. oxygen)
- Toxic (e.g. chlorine, phosgene)
Class 3 Flammable liquids
Class 4.1 Flammable solids, self-reactive substances, and solid desensitized explosives
Class 4.2 Substances liable to spontaneous combustion
Class 4.3 Substances which, in contact with water, emit flammable gases
Class 5.1 Oxidizing substances
Class 5.2 Organic peroxides
Class 6.1 Toxic substances
Class 6.2 Infectious substances
Class 7 Radioactive material
Class 8 Corrosive substances
Class 9 Miscellaneous dangerous substances and articles

Each entry in the different classes has been assigned a 4 digit UN number. It is not usually possible to deduce the hazard class of a substance from its UN number: they have to be looked up in a table. An exception to this are Class 1 substances whose UN number will always begin with a 0. See List of UN numbers.

Tunnel classifications

The sign to the left of the Blackwall Tunnel approach road shows Class E.

The ADR Secretariat has defined a classification system for major tunnels in Europe. "The categorization [is] based on the assumption that in tunnels there are three major dangers [that] may cause numerous victims or serious damage to the tunnel structure." It is the responsibility of each national authority to categorize its tunnels accordingly. The classes ranges from A (least restrictive), to E (most restrictive). As of 2010, in the United Kingdom for example, the least restrictive was the tunnel carrying the A299 to the Port of Ramsgate, while the most restrictive were several tunnels in East London, including the Limehouse Link tunnel, the Rotherhithe Tunnel, the Blackwall Tunnel and the East India Dock Link Tunnel.