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Copper(II) azide

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Copper(II) azide
Copper (II) azide.JPG
Names
IUPAC name
Copper(II) azide
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
UNII
  • InChI=1S/Cu.2N3/c;2*1-3-2/q+2;2*-1 checkY
    Key: SXHYOTRZGGGMEV-UHFFFAOYSA-N checkY
  • InChI=1/Cu.2N3/c;2*1-3-2/q+2;2*-1
    Key: SXHYOTRZGGGMEV-UHFFFAOYAL
  • [N-]=[N+]=[N-][Cu+2][N-]=[N+][N-]
  • [Cu+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-]
Properties
Cu(N3)2
Molar mass 147.586 g/mol
Appearance brown orthorhombic crystals
Density 2.6 g/cm3
Melting point Explodes when heated
Hazards
GHS labelling:
GHS01: ExplosiveGHS06: Toxic
Danger
NFPA 704 (fire diamond)
3
0
4
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Related compounds
Other cations
Lead(II) azide
Silver azide
Sodium azide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Copper(II) azide is a medium density explosive with the molecular formula Cu(N3)2.

Uses

Copper azide is very explosive and is too sensitive for any practical use unless handled in solution.

Preparation

Copper azide can be prepared by a metathesis reaction between water-soluble sources of Cu2+ and azide ions. (Spectator ions omitted in reaction below).

Cu2+ + 2 N3 → Cu(N3)2

It can be destroyed by concentrated nitric acid to form non-explosive products, these being nitrogen, nitrogen oxides and copper(II) nitrate.



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