Мы используем файлы cookie.
Продолжая использовать сайт, вы даете свое согласие на работу с этими файлами.
Carbohydrate
Methanediol
Другие языки:

Methanediol

Подписчиков: 0, рейтинг: 0
Methanediol
Skeletal formula of methanediol with some explicit hydrogens added
Spacefill model of methanediol
Ball and stick model of the methanediol
Names
Preferred IUPAC name
Methanediol
Other names
  • Formaldehyde hydrate
  • Formaldehyde monohydrate
  • Methylene glycol
Identifiers
3D model (JSmol)
Abbreviations MADOL
1730798
ChEBI
ChemSpider
ECHA InfoCard 100.006.673
EC Number
  • 207-339-5
PubChem CID
UNII
  • InChI=1S/CH4O2/c2-1-3/h2-3H,1H2 checkY
    Key: CKFGINPQOCXMAZ-UHFFFAOYSA-N checkY
  • OCO
Properties
CH4O2
Molar mass 48.041 g·mol−1
Appearance Colourless liquid
Density 1.199 g/cm3
Boiling point 194 °C (381 °F; 467 K) at 101 kPa
Vapor pressure 16.1 Pa
Acidity (pKa) 13.29
1.401
Hazards
Flash point 99.753 °C (211.555 °F; 372.903 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Methanediol, also known as formaldehyde monohydrate or methylene glycol, is an organic compound with chemical formula CH2(OH)2. It is the simplest geminal diol. In aqueous solutions it coexists with oligomers (short polymers). The compound is closely related and convertible to the industrially significant derivatives paraformaldehyde ((CH2O)n), formaldehyde (H2C=O), and 1,3,5-trioxane ((CH2O)3).

Methanediol is a product of the hydration of formaldehyde. The equilibrium constant for hydration is estimated to be 103,CH2(OH)2 predominates in dilute (<0.1%) solution. In more concentrated solutions, it oligomerizes to HO(CH2O)nH.

Occurrence

The dianion, methanediolate, is believed to be an intermediate in the crossed Cannizzaro reaction.

Gaseous methanediols can be generated by electron irradiation and sublimation of a mixture of methanol and oxygen ices.

Methanediol is believed to occur as an intermediate in the decomposition of carbonyl compounds in the atmosphere, and as a product of ozonolysis on these compounds.

Safety

Methanediol, rather than formaldehyde, is listed as one of the main ingredients of "Brazilian blowout", a hair-straightening formula marketed in the United States. The equilibrium with formaldehyde has caused concern since formaldehyde in hair straighteners is a health hazard, but the risk has been disputed.

See also


Новое сообщение