Мы используем файлы cookie.
Продолжая использовать сайт, вы даете свое согласие на работу с этими файлами.
Poison
Nitrocyclohexane
Другие языки:

Nitrocyclohexane

Подписчиков: 0, рейтинг: 0
Nitrocyclohexane
Nitrocyclohexane.svg
Nitrocyclohexane molecule spacefill.png
Names
IUPAC name
Nitrocyclohexane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.050
PubChem CID
UNII
  • InChI=1S/C6H11NO2/c8-7(9)6-4-2-1-3-5-6/h6H,1-5H2
    Key: NJNQUTDUIPVROZ-UHFFFAOYSA-N
  • InChI=1/C6H11NO2/c8-7(9)6-4-2-1-3-5-6/h6H,1-5H2
    Key: NJNQUTDUIPVROZ-UHFFFAOYAA
  • [O-][N+](=O)C1CCCCC1
Properties
C6H11NO2
Molar mass 129.159 g·mol−1
Density 1.061 g/cm3
Melting point −34 °C (−29 °F; 239 K)
Boiling point 205.8 °C (402.4 °F; 478.9 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Nitrocyclohexane is an organic compound with the molecular formula C6H11NO2. It is a colorless liquid, but degraded samples appear pale yellow.

Preparation

It is prepared by reaction of nitrogen dioxide with cyclohexane. Cyclohexane is a convenient substrate because all twelve C-H bonds are equivalent, so mononitration does not give isomers (unlike the case of n-hexane).

Hazards

Nitrocyclohexane is highly flammable and a strong oxidizing agent. It is listed as an extremely hazardous substance by the Emergency Planning and Community Right-to-Know Act, and the NOAA warns that it can be explosive.

Further reading

  • Iffland, Don C.; Criner, G. X. (1953). "Preparation of Nitro Compounds from Oximes. II. The Improved Synthesis of Nitrocycloalkanes1". Journal of the American Chemical Society. 75 (16): 4047. doi:10.1021/ja01112a049.
  • Fahim, Hussein; Fleifel, Abdallah; Fahim, Fawzia (1960). "Synthesis of 1-Benzylnaphthalenes". The Journal of Organic Chemistry. 25 (6): 1040–1041. doi:10.1021/jo01076a605.

Новое сообщение